Submitted by 321ECRAB123 t3_10jj283 in explainlikeimfive
Lithuim t1_j5kualk wrote
Reply to comment by 321ECRAB123 in Eli5: do noble gases really have full valence shells by 321ECRAB123
“Valence” refers to the highest level of orbital(s) where electrons relatively freely wander between structures with similar energy levels. How many electrons this is will vary with atomic size.
1s is the lowest orbital, and has no friends - so helium’s valence shell is just two electrons.
Then there’s a big jump.
2s is similar in energy to 2p, and so electrons will move between the two. To fill this next valence layer you need eight electrons.
Then there’s a big jump
3s is similar to 3p, again giving you an 8-valence level.
Then there’s a big jump.
4s is where you’re now at energy levels high enough to generate a d-orbital, and 4s, 3d, and 4p form all sorts of wacky structures. This layer has 18 in the valence level.
Then… you guessed it… there’s a big jump.
“Full valence” is where these big jumps occur. Adding or subtracting an electron from a full structure is relatively difficult. You’re either forming an entirely new structure on top of the existing one or destabilizing a fully spin-paired configuration. Both are difficult, and so atoms and ions with full valence are highly chemically stable.
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