> How the temperature relates to other state variables is different (and difficult!) in liquids but that doesn't apply to kinetic energy

Is there a simple explanation for why this is the case? Given the presence of intermolecular potentials (which are not quadratic terms), I wouldn't expect equipartition to hold. Is the argument that this effect is negligible, and if so, how does one argue that it is?

Furthermore, does your calculation account for vibrational and rotational modes?

If you could point me to sources that cover these questions, I'd be very grateful. Thanks.