Submitted by FreakinGeese t3_123141v in askscience
Dielectric breakdown is an issue but there are materials (diamond, Teflon, ultra-high vacuum) that only break down at absurdly high voltages.
If you want the most bang for your buck (both volume and mass wise) why not step up the voltage a capacitor charges at super duper high? Then the energy of the capacitor is proportional to the volume * permittivity * dielectric strength ^2. Why not have a centimeter of diamond between two plates with a potential difference of a million or so volts? That’s good energy density right there. According to my calculations, diamond capacitors should have somewhere around a hundredth the volumetric energy density of gasoline, which really isn’t that bad for certain applications
drhunny t1_jdv6sgs wrote
I've done r&d with materials in a similar situation. One problem is surface leakage paths. You can't just think of the cap as a simple component anymore. The case, mounting, humidity, vibration, etc can cause a sudden short circuit. Literally breathing on the circuit could cause it to explode. So now you have to can it in transformer oil or similar. That's got its own set of headaches.